Consider the following four compounds I, II, III, and IV. array l I II III IV array…

Chemistry · JEE Advanced · NTA ExamsBasic Principles of Organic Chemistry

Consider the following four compounds I, II, III, and IV.
\[\begin{array}{l} \\ \text { I }\\ \\ \text { II }\\ \\ \text { III }\\ \\ \text { IV } \end{array}\] 
Choose the correct statement(s). (2020/Shift-2)
  1. The order of basicity is II > I > III > IV.
  2. The magnitude of \(\mathrm{pK}_{\mathrm{b}}\)difference between I and II is more than that between III and IV.
  3. Resonance effect is more in III than in IV.
  4. Steric effect makes compound IV more basic than III.

Answer

(C) Resonance effect is more in III than in IV., (D) Steric effect makes compound IV more basic than III.

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