These 3 questions deal with the following chemical reaction: (green solution) Ni ^ 2+ (…

Chemistry · JEE Advanced · NTA ExamsEquilibrium


These 3 questions deal with the following chemical reaction:
\(\underset{\text { (green solution) }}{\mathrm{Ni}^{2+}(\mathrm{aq})}+6 \mathrm{NH}_{3}(\mathrm{aq}) \rightleftharpoons \underset{\text { (BheSolution) }}{\left[\mathrm{Ni}\left(\mathrm{NH}_{3}\right)_{6}\right]^{2+}(\mathrm{aq})}\)
When H+(aq) is added, the colour green is favoured. Use one or more of the following interpretations to answer the questions.
I. Some unreacted Ni2+ (aq) is present in the solution at equilibrium.
II. Some unreacted NH3 (aq) is present in the solution at equilibrium.
III. The colour change indicates new equilibrium conditions with reduced [Ni(NH3)6]2+(aq).
IV. The colour change indicates new equilibrium conditions with increased [Ni(NH3)6]2+(aq).
 
The deepening colour on addition of more NH3(aq) supports intepretation(s)
  1. I only
  2. I and IV only
  3. I and II only
  4. II and IV only

Answer

(B) I and IV only

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