If S + O 2 → SO 2 ∆H = –298.2 kJ SO _ 2 + 1 2 O _ 2 SO _ 3 ∆H = –98.2 kJ SO _ 3 + H _ 2 O…
Chemistry · JEE Main · NTA Exams — Chemical Thermodynamics
If S + O2 \(\text { → }\) SO2 ∆H = –298.2 kJ
\(\mathrm{SO}_{2}+\frac{1}{2} \mathrm{O}_{2} \longrightarrow \mathrm{SO}_{3}\) ∆H = –98.2 kJ
\(\mathrm{SO}_{3}+\mathrm{H}_{2} \mathrm{O} \longrightarrow \mathrm{H}_{2} \mathrm{SO}_{4}\) ∆H = –130.2 kJ
\(\mathrm{H}_{2}+\frac{1}{2} \mathrm{O}_{2} \longrightarrow \mathrm{H}_{2} \mathrm{O}\) ∆H = –287.3 kJ
the enthalpy of formation of H2SO4 at 298 K will be
\(\mathrm{SO}_{2}+\frac{1}{2} \mathrm{O}_{2} \longrightarrow \mathrm{SO}_{3}\) ∆H = –98.2 kJ
\(\mathrm{SO}_{3}+\mathrm{H}_{2} \mathrm{O} \longrightarrow \mathrm{H}_{2} \mathrm{SO}_{4}\) ∆H = –130.2 kJ
\(\mathrm{H}_{2}+\frac{1}{2} \mathrm{O}_{2} \longrightarrow \mathrm{H}_{2} \mathrm{O}\) ∆H = –287.3 kJ
the enthalpy of formation of H2SO4 at 298 K will be
- –433.7 kJ
- –650.3 kJ
- +320.5 kJ
- –813.9 kJ
Answer
(D) –813.9 kJ
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