In an irreversible process taking place at constant T and P and in which only…

Chemistry · JEE Main · NTA ExamsChemical Thermodynamics

In an irreversible process taking place at constant T and P and in which only pressure-volume work is being done, the change in Gibbs' free energy (dG) and change in entropy (dS), satisfy the criteria:
  1. (dS)V, E < 0, (dG)T, P < 0
  2. (dS)V, E > 0, (dG)T, P < 0
  3. (dS)V, E = 0, (dG)T, P = 0
  4. (dS)V, E = 0, (dG)T, P > 0

Answer

(A) (dS) V, E < 0, (dG) T, P < 0

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