Given below are two statements: Statement I: Aniline reacts with con. H 2 SO 4 followed…

Chemistry · JEE Main · NTA ExamsOrganic Compounds Containing Nitrogen

Given below are two statements:
 Statement I: Aniline reacts with con. H2SO4 followed by heating at 453 –473K gives p-aminobenzene sulphonic acid, which gives blood red colour in the 'Lassaigne's test'.
 Statement II: In Friedel-Craft's alkylation and acylation reactions, aniline forms salt with the \(\mathrm{AlCl}_{3}\)catalyst.
 Due to this, nitrogen of aniline acquires a positive charge and acts as deactivating group.
 In the light of the above statements, choose the correct answer from the options given below:
(Jee Main 2024)
  1. Statement I is false but statement II is true.
  2. Both statement I and statement II are false.
  3. Statement I is true but statement II is false.
  4. Both statement I and statement II are true.

Answer

(D) Both statement I and statement II are true.

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