Among the following options, select the option in which each complex in Set-I shows…
Chemistry · JEE Advanced · NTA Exams — Coordination Compounds
Among the following options, select the option in which each complex in Set-I shows geometrical isomerism and the two complexes in Set-II are ionization isomers of each other.
[en = H2NCH2CH2NH2] (2024)
[en = H2NCH2CH2NH2] (2024)
- Set-I: [Ni(CO)4] and [PdCl2(PPh3)2] Set-II: [Co(NH3)5Cl] SO4 and [Co(NH3)5(SO4)]Cl
- Set-I: [Co(en)(NH3)2Cl2] and [PdCl2(PPh3)2] Set-II: [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6]
- Set-I: [Co(NH3)3(NO2)3] and [Co(en)2Cl2] Set-II: [Co(NH3)5Cl]SO4 and [Co(NH3)5(SO4)]Cl
- Set-I: [Cr(NH3)5Cl]Cl2 and [Co(en)(NH3)2Cl2] Set-II: [Cr(H2O)6]Cl3 and [Cr(H2O)5Cl]Cl2 · H2O
Answer
(C) Set-I: [Co(NH 3 ) 3 (NO 2 ) 3 ] and [Co(en) 2 Cl 2 ] Set-II: [Co(NH 3 ) 5 Cl]SO 4 and [Co(NH 3 ) 5 (SO 4 )]Cl
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