Ag + NH 3 ⇌ [Ag(NH 3 ) + ] ; k 1 = 6.8 × 10 –3 [Ag(NH 3 )] + + NH 3 ⇌ [Ag(NH 3 ) 2 ] + …

Chemistry · JEE Advanced · NTA ExamsChemical Kinetics

Ag+ NH3 \(\text { ⇌ }\) [Ag(NH3)+] ; k1 = 6.8 × 10–3
[Ag(NH3)]+ + NH3 \(\text { ⇌ }\) [Ag(NH3)2]+ ; k2 = 1.6 × 10–3
then the formation constant of [Ag(NH3)2]+ is (2006)
  1. 6.8 × 10–6
  2. 1.08 × 10–5
  3. 1.08 × 10–6
  4. 6.8 × 10–5

Answer

(B) 1.08 × 10 –5

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