Amongst Ni(CO) 4 , [Ni(CN) 4 ] 2 – and NiCl 4 2 – ,

Chemistry · JEE Advanced · NTA ExamsCoordination Compounds

Amongst Ni(CO)4, [Ni(CN)4]2 and NiCl42,
  1. Ni(CO)4 and NiCl42 are diamagnetic [Ni(CN)4]2 is paramagnetic.
  2. NiCl42 and [Ni(CN)4]2 are diamagnetic and Ni(CO)4 is paramagnetic.
  3. Ni(CO)4 and [Ni(CN)4]2 are diamagnetic and NiCl42 is paramagnetic.
  4. Ni(CO)4 is diamagnetic and NiCl42 and [Ni(CN)4]2 are paramagnetic.

Answer

(C) Ni(CO) 4 and [Ni(CN) 4 ] 2 – are diamagnetic and NiCl 4 2 – is paramagnetic.

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