Amongst Ni(CO) 4 , [Ni(CN) 4 ] 2 – and NiCl 4 2 – ,

Chemistry · JEE Advanced · NTA Exams — Coordination Compounds

Amongst Ni(CO)4, [Ni(CN)4]2– and NiCl42–,
  1. Ni(CO)4 and NiCl42– are diamagnetic [Ni(CN)4]2– is paramagnetic.
  2. NiCl42– and [Ni(CN)4]2– are diamagnetic and Ni(CO)4 is paramagnetic.
  3. Ni(CO)4 and [Ni(CN)4]2– are diamagnetic and NiCl42– is paramagnetic.
  4. Ni(CO)4 is diamagnetic and NiCl42– and [Ni(CN)4]2– are paramagnetic.

Answer

(C) Ni(CO) 4 and [Ni(CN) 4 ] 2 – are diamagnetic and NiCl 4 2 – is paramagnetic.

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