These 3 questions refer to the following experiment. Some Fe(NO 3 ) 3 solution is added…

Chemistry · JEE Advanced · NTA ExamsEquilibrium


These 3 questions refer to the following experiment. Some Fe(NO3)3 solution is added to KSCN solution and a dark red colour appears. This colour is caused by [Fe(SCN)]2+, which is formed by the reaction :
Fe3+ (aq) + SCN (aq) \(\text { ⇌ }\) [Fe(SCN)]2+
Experiments show this colour becomes deeper upon addition of more Fe(NO3)3 or KSCN. The colour disappears when Na2HPO4 is added. Use one or more of the interpretations below.
(a ) Unreacted Fe3+ (aq) is present in the original equilibrium mixture.
(b ) Unreacted SCN (aq) is present in the original equilibrium mixture.
(c ) Colour change indicates a new equilibrium ;
[Fe(SCN)2+ (aq)] has been reduced.
(d ) Colour change indicates a new equilibrium ;
[Fe(SCN)2+ (aq)] has been increased.
The disappearance of colour on addition of Na2HPO4 supports
  1. A only
  2. A and D only
  3. A and B only
  4. C only

Answer

(D) C only

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