p-Amino-N,N-dimethylaniline is added to a strongly acidic solution of X. The resulting…

Chemistry · JEE Advanced · NTA ExamsPrinciples Related To Practical Chemistry

p-Amino-N,N-dimethylaniline is added to a strongly acidic solution of X. The resulting solution is treated with a few drops of aqueous solution of Y to yield a blue colouration due to the formation of methylene blue. Treatment of the aqueous solution of Y with the reagent potassium hexacyanoferrate(II) leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, treatment of the solution of Y with the solution of potassium hexacyanoferrate(III) leads to a brown colouration due to the formation of Z.

The compound Z is
  1. Mg2[Fe(CN)6]
  2. Fe[Fe(CN)6]
  3. Fe4[Fe(CN)6]3
  4. K2Zn3[Fe(CN)6]2

Answer

(C) Fe 4 [Fe(CN) 6 ] 3

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