An aqueous solution of a mixture of two inorganic salts, when treated with dilute HCl…

Chemistry · JEE Advanced · NTA ExamsPrinciples Related To Practical Chemistry

An aqueous solution of a mixture of two inorganic salts, when treated with dilute HCl, gave a precipitate (P) and a filtrate (Q). The precipitate P was found to dissolve in hot water. The filtrate (Q) remained unchanged, when treated with H2S in a dilute mineral acid medium. However, it gave a precipitate (R) with H2S in an ammoniacal medium. The precipitate R gave a coloured solution (S), when treated with H2O2 in an aqueous NaOH medium.

The precipitate P contains
  1. Pb2+
  2. Hg22+
  3. Ag+
  4. Hg2+

Answer

(A) Pb 2+

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