In a bimolecular reaction, the steric factor P was experimentaly determined to be 4.5 …

Chemistry · JEE Advanced · NTA ExamsChemical Kinetics

In a bimolecular reaction, the steric factor P was experimentaly determined to be 4.5 . the correct option(s) among the following is (are) (2017)
  1. The activation energy of the reaction is unaffected by the value of the steric factor
  2. Experimentally determined value of frequency factor is higher than that predicted by Arrhenius equation
  3. The value of frequency factor predicted by Arrhenius equation is higher than that determined experimentally
  4. Since P = 4.5, the reaction will not proceed unless an effective catalyst is used

Answer

(A) The activation energy of the reaction is unaffected by the value of the steric factor, (B) Experimentally determined value of frequency factor is higher than that predicted by Arrhenius equation

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