These 3 questions refer to the following experiment. Some Fe(NO 3 ) 3 solution is added…
Chemistry · JEE Advanced · NTA Exams — Equilibrium
These 3 questions refer to the following experiment. Some Fe(NO3)3 solution is added to KSCN solution and a dark red colour appears. This colour is caused by [Fe(SCN)]2+, which is formed by the reaction :
Fe3+ (aq) + SCN– (aq) \(\text { ⇌ }\) [Fe(SCN)]2+
Experiments show this colour becomes deeper upon addition of more Fe(NO3)3 or KSCN. The colour disappears when Na2HPO4 is added. Use one or more of the interpretations below.
(a ) Unreacted Fe3+ (aq) is present in the original equilibrium mixture.
(b ) Unreacted SCN– (aq) is present in the original equilibrium mixture.
(c ) Colour change indicates a new equilibrium ;
[Fe(SCN)2+ (aq)] has been reduced.
(d ) Colour change indicates a new equilibrium ;
[Fe(SCN)2+ (aq)] has been increased.
The deepening of colour on addition of more Fe(NO3)3 supports
- A only
- A and D only
- A and B only
- B and D only
Answer
(D) B and D only
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