Volume of the flask in which the following equilibria are separately established are…

Chemistry · JEE Advanced · NTA ExamsEquilibrium

Volume of the flask in which the following equilibria are separately established are transferred to a flask that is double the size of the earlier flask. In which of the following cases, equilibrium constants are affected ?
  1. \(\mathrm{N}_{2(\mathrm{~g})}+\mathrm{H}_{2(\mathrm{~g})}\) \(\text { ⇌ }\)\(2 \mathrm{NH}_{3(\mathrm{~g})},\) exothermic
  2. \(\mathrm{N}_{2(\mathrm{~g})}+\mathrm{O}_{2(\mathrm{~g})}\)\(\text { ⇌ }\)\(2 \mathrm{NO}_{(\mathrm{g})},\)endothermic
  3. \(\mathrm{PCl}_{5(\mathrm{~g})}\)\(\text { ⇌ }\)\(\mathrm{PCl}_{3(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})},\) endothermic
  4. none of these

Answer

(D) none of these

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