A coordination compound X gives pale yellow colour with AgNO 3 solution while its isomer…

Chemistry · Class 12 · CBSECoordination Compounds

A coordination compound X gives pale yellow colour with AgNO3 solution while its isomer Y gives white precipitate with BaCl2. Two compounds are isomers of CoBrSO4⋅5NH3. What could be the possible formula of X and Y?

  1. X = [Co(NH3)5SO4]Br, Y = [Co(NH3)5Br]SO4
  2. X = [Co(NH3)5Br]SO4, Y = [Co(NH3)5SO4]Br
  3. X = [Co(NH3)5Br(SO4)], Y = [CoBr(SO4)(NH3)5]
  4. X = [Co(Br)5NH3]SO4, Y = [CoBr(SO4)]NH3

Answer

(A) X = [Co(NH 3 ) 5 SO 4 ]Br, Y = [Co(NH 3 ) 5 Br]SO 4

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