A solution containing a mixture of 0.05 M NaCl and 0.05 M Nal is taken. (K sp of AgCl =…

Chemistry · JEE Advanced · NTA ExamsEquilibrium

A solution containing a mixture of 0.05 M NaCl and 0.05 M Nal is taken. (Ksp of AgCl = 10–10 and Ksp of
AgI = 4 × 10–16). When AgNO3 is added to such a solution:
  1. the concentration of Ag+ required to precipitate Cl is 2 × 10–9 mol/L
  2. the concentration of Ag+ required to precipitate I is 8 × 10–15 mol/L
  3. AgCl and AgI will be precipitate together
  4. first AgI will be precipitated

Answer

(A) the concentration of Ag + required to precipitate Cl – is 2 × 10 –9 mol/L, (B) the concentration of Ag + required to precipitate I – is 8 × 10 –15 mol/L, (D) first AgI will be precipitated

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