Equivalent weight = n-factor is very important in redox as well as non-redox reactions…
Chemistry · JEE Advanced · NTA Exams — Some Basic Concepts in Chemistry
Equivalent weight =
n-factor is very important in redox as well as non-redox reactions. With the help of n-factor we can predicts the molar ratio of the reactant species taking part in reactions. The reciprocal of n-factor’s ratio of the reactants is the molar ratio of the reactants.
In general n-factor of acid/base is number of moles of
H+/OH– furnished per mole of acid/base. n-factor of a reactant is no. of moles of electrons lost or gained per mole of reactant.
Example 1 :
1 . In acidic medium : \(\mathrm{KMnO}_{4}(\mathrm{n}=5) \rightarrow \mathrm{Mn}^{2+}\)
2 . In neutral medium : \(\mathrm{KMnO}_{4}(\mathrm{n}=3) \rightarrow \mathrm{Mn}^{2+}\)
3 . In basic medium : \(\mathrm{KMnO}_{4}(\mathrm{n}=1) \rightarrow \mathrm{Mn}^{6+}\)
Example 2 :
\(\mathrm{FeC}_{2} \mathrm{O}_{4} \rightarrow \mathrm{Fe}^{3+}+2 \mathrm{CO}_{2}\)
Total no. of moles of e– lost by 1 mole of FeC2O4
= 1 + 1 × 2 \(\text { ⇒ }\) 3
\(\text { ∴ }\) n-factor of FeC2O4 = 3
For the reaction,
\(\mathrm{H}_{3} \mathrm{PO}_{2}+\mathrm{NaOH} \rightarrow \mathrm{NaH}_{2} \mathrm{PO}_{2}+\mathrm{H}_{2} \mathrm{O}\)
What is the equivalent weight of H3PO2? (mol. wt. is M)
- M
- M/2
- M/3
- None of these
Answer
(A) M
Sign up free on Edukali to view the step-by-step worked solution and practice thousands of similar questions.
Related practice questions
- If we consider that 1/6 in place of 1/12, mass of carbon atom is taken to be the relative atomic mass unit…
- Assertion (A) : The equivalent mass of an element is variable. Reason (R) : It depends on the valency of the…
- An element A in a compound ABD has oxidation number –n. It is oxidised by Cr 2 O 7 2– in acidic medium. In…
- Which of the following statements is/are correct ? 20.0 mL of 6.0 M HCl is mixed with 50.0 mL of 2.0 M Ba(OH)…
- At room temperature, disproportionation of an aqueous solution of in situ generated nitrous acid (HNO 2 )…
- In van der Waals equation of state for a non-ideal gas, the term that accounts for intermolecular forces is
- Equal volumes of 0.200 M HCl and 0.400M KOH are mixed. The concentrations of the ions in the resulting…
- Calorie is defined as the amount of heat required to raise temperature of 1 g of water by 1°C and it is…
More Some Basic Concepts in Chemistry questions · Browse all practice questions