A solution containing 2.67 g of CoCl 3 .6NH 3 (molar mass = 267.5 g mol -1 ) is passed…

Chemistry · JEE Main · NTA ExamsCoordination Compounds

A solution containing 2.67 g of CoCl3.6NH3 (molar mass = 267.5 g mol-1) is passed through a cation exchanger.  The chloride ions obtained in solution were treated with excess of AgNO(molar mass  = 170 g mol-1 ) to give 4.78 g of AgCl. (molar mass = 143.5g mol-1).  The formula of the complex is: 
  1. [Co(NH3)6]Cl3
  2. [CoCl2(NH3)4]Cl
  3. [CoCl3(NH3)3]
  4. [CoCl(NH3)5]Cl2

Answer

(D) [CoCl(NH 3 ) 5 ]Cl 2

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