Gold is noble to react with nitric acid. However, gold does react with aqua regia because…

Chemistry · JEE Main · NTA ExamsRedox Reactions and Electrochemistry

Gold is noble to react with nitric acid. However, gold does react with aqua regia because of the formation of complex ion \(\mathrm{AuCl}_{4}^{-}\). Consider the following half-reactions:

\[\begin{array}{l} A u^{3+}(a q)+3 e^{-} \longrightarrow A u(5): E^{\prime \prime}=1.5 \mathrm{~V} \\ A u C_{4}^{-}(a q)+3 e^{-} \longrightarrow \mathrm{Au}(5)+4 C^{-}(a q): E^{\prime \prime}=1 \mathrm{~V} \end{array}\]

Using the above data, calculate the formation constant for \(\mathrm{AuCl}_{4}^{-}\) at 25°C.

  1. 3.1 x 1010
  2. 2.33 x 1025
  3. 4 x 1016
  4. 3.3 x 1020

Answer

(B) 2.33 x 10 25

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