In the scheme given below, X and Y , respectively, are array ll Metal halide aq. NaOH &…
Chemistry · JEE Advanced · NTA Exams — d- and f-Block Elements
In the scheme given below, X and Y, respectively, are
\[\begin{array}{ll} \text { Metal halide } \xrightarrow{\text { aq. } \mathrm{NaOH}} & \begin{array}{c} \text { White precipitate }(P) \\ + \\ \text { Filtrate }(Q) \end{array} \\ P \xrightarrow[\text { heat }]{\substack{a q . \mathrm{H}_{2} \mathrm{SO}_{4} \\ \mathrm{PbO}_{2} \text { (excess) }}} X & \text { (a coloured species in solution) } \\ Q \xrightarrow[\text { warm }]{\mathrm{MnO}(\mathrm{OH})_{2},} \text { Conc. } \mathrm{H}_{2} \mathrm{SO}_{4} \\ Q & \begin{array}{l} \text { (gives blue-colouration with } \\ \text { KI-starch paper) } \end{array} \end{array}\]
\[\begin{array}{ll} \text { Metal halide } \xrightarrow{\text { aq. } \mathrm{NaOH}} & \begin{array}{c} \text { White precipitate }(P) \\ + \\ \text { Filtrate }(Q) \end{array} \\ P \xrightarrow[\text { heat }]{\substack{a q . \mathrm{H}_{2} \mathrm{SO}_{4} \\ \mathrm{PbO}_{2} \text { (excess) }}} X & \text { (a coloured species in solution) } \\ Q \xrightarrow[\text { warm }]{\mathrm{MnO}(\mathrm{OH})_{2},} \text { Conc. } \mathrm{H}_{2} \mathrm{SO}_{4} \\ Q & \begin{array}{l} \text { (gives blue-colouration with } \\ \text { KI-starch paper) } \end{array} \end{array}\]
- CrO42– and Br2
- MnO42– and Cl2
- MnO4– and Cl2
- MnSO4 and HOCl
Answer
(C) MnO 4 – and Cl 2
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