Standard electrode potential data are useful for understanding the suitability of an…
Chemistry · JEE Advanced · NTA Exams — Some Basic Concepts in Chemistry
Standard electrode potential data are useful for understanding the suitability of an oxidant in a redox titration. Some half cell reactions and their standard potentials are given below :
\(\mathrm{MnO}_{4(a q)}^{-}+8 \mathrm{H}_{(a q)}^{+}+5 e^{-} \rightarrow \mathrm{Mn}_{(a q)}^{2+}+4 \mathrm{H}_{2} \mathrm{O}_{(l)}\)
; E° = 1.51 V
\(\mathrm{Cr}_{2} \mathrm{O}_{7(a q)}^{2-}+14 \mathrm{H}_{(a q)}^{+}+6 e^{-} \rightarrow 2 \mathrm{Cr}_{(a q)}^{3+}+7 \mathrm{H}_{2} \mathrm{O}\)
; E° = 1.38 V
\(\mathrm{Fe}_{(a q)}^{3+}+e^{-} \rightarrow \mathrm{Fe}_{(a q)}^{2+}\) ; E° = 0.77 V
\(\mathrm{Cl}_{2(g)}+2 e^{-} \rightarrow 2 \mathrm{Cl}_{(a q)}^{-}\); E° = 1.40 V
Identify the only incorrect statement regarding the quantitative estimation of aqueous Fe(NO3)2.
\(\mathrm{MnO}_{4(a q)}^{-}+8 \mathrm{H}_{(a q)}^{+}+5 e^{-} \rightarrow \mathrm{Mn}_{(a q)}^{2+}+4 \mathrm{H}_{2} \mathrm{O}_{(l)}\)
; E° = 1.51 V
\(\mathrm{Cr}_{2} \mathrm{O}_{7(a q)}^{2-}+14 \mathrm{H}_{(a q)}^{+}+6 e^{-} \rightarrow 2 \mathrm{Cr}_{(a q)}^{3+}+7 \mathrm{H}_{2} \mathrm{O}\)
; E° = 1.38 V
\(\mathrm{Fe}_{(a q)}^{3+}+e^{-} \rightarrow \mathrm{Fe}_{(a q)}^{2+}\) ; E° = 0.77 V
\(\mathrm{Cl}_{2(g)}+2 e^{-} \rightarrow 2 \mathrm{Cl}_{(a q)}^{-}\); E° = 1.40 V
Identify the only incorrect statement regarding the quantitative estimation of aqueous Fe(NO3)2.
- MnO4– can be used in aqueous HCl.
- Cr2O72– can be used in aqueous HCl.
- MnO4– can be used in aqueous H2SO4.
- Cr2O72– can be used in aqueous H2SO4.
Answer
(A) MnO 4 – can be used in aqueous HCl.
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