Compound A (molecular formula C 3 H 8 O) is treated with acidified potassium dichromate…

Chemistry · JEE Advanced · NTA ExamsAldehydes and Ketones

Compound A (molecular formula C3H8O) is treated with acidified potassium dichromate to form a product B (molecular formula C3H6O). B forms a shining silver mirror on warming with ammonical silver nitrate. B when treated with an aqueous solution of H2NCONHNH2 and sodium acetate gives a product C. Identify the structure of C. (2002)
  1. \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}=\mathrm{N} . \mathrm{NHCONH}_{2}\)
  2. \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}=\mathrm{N} . \mathrm{CONHNH}{ }_{2}\)

Answer

(A) CH _ 3 CH _ 2 CH = N . NHCONH _ 2

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