Consider the following reaction sequence, K _ 4 [ Fe ( CN )_ 5 ]+ ( CONC ) H _ 2 SO _ 4 +…

Chemistry · NEET · NTA Examsp-Block Elements

Consider the following reaction sequence,

\(\mathrm{K}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{5}\right]+\underset{(\mathrm{CONC})}{\mathrm{H}_{2} \mathrm{SO}_{4}}+\mathrm{H}_{2} \mathrm{O} \xrightarrow{\Delta} \mathrm{~K}_{2} \mathrm{5O}_{4}+\mathrm{FeSO}_{4}+3\left(\mathrm{NH}_{4}\right)_{2} \mathrm{SO}_{4}+\underset{(\mathrm{gas})}{(\mathrm{A})}\)

Now, consider the following statement about gas (A):

  1. Gas (A) reduces ammonical silver nitrate to silver (black), in absence of other gaseous reducing agents.
  2. Gas (A) is Lewis base
  3. Gas (A) is quantitatively estimated by reaction with iodine pentaoxide.
  4. Gas (A) is amphoteric.

Select incorrect statement(s) about gas 'A':

  1. I, III, IV only
  2. I, IV only
  3. IV only
  4. None of these

Answer

(C) IV only

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