Volume of the flask in which the following equilibria are separately established are…

Chemistry · JEE Advanced · NTA ExamsEquilibrium

Volume of the flask in which the following equilibria are separately established are transferred to a flask that is double the size of the earlier flask. In which of the following cases, equilibrium concentrations are affected ?
  1. \(\mathrm{N}_{2}(\mathrm{~g})+3 \mathrm{H}_{2}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NH}_{3}(\mathrm{~g})\)
  2. \(\mathrm{N}_{2}(\mathrm{~g})+\mathrm{O}_{2}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NO}(\mathrm{~g})\)
  3. \(\mathrm{PCl}_{5}(\mathrm{~g}) \rightleftharpoons \mathrm{PCl}_{3}(\mathrm{~g})+\mathrm{Cl}_{2}(\mathrm{~g})\)
  4. \(2 \mathrm{NO}(\mathrm{~g}) \rightleftharpoons \mathrm{N}_{2}(\mathrm{~g})+\mathrm{O}_{2}(\mathrm{~g})\)

Answer

(A) N _ 2 ( ~g )+3 H _ 2 ( ~g ) 2 NH _ 3 ( ~g ), (C) PCl _ 5 ( ~g ) PCl _ 3 ( ~g )+ Cl _ 2 ( ~g )

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