For the reactions (I) (II) (III) (IV) The correct decreasing order of enthalpies of…

Chemistry · JEE Main · NTA ExamsSome Basic Principles of Organic Chemistry

For the reactions
(I)  
(II)  
(III)  
(IV)  
 
The correct decreasing order of enthalpies of reaction for producing carbocation is
  1. \(\Delta \mathrm{H}_{1}^{\circ}>\Delta \mathrm{H}_{2}^{\circ}>\Delta \mathrm{H}_{3}^{\circ}>\Delta \mathrm{H}_{4}^{\circ}\)
  2. \(\Delta \mathrm{H}_{4}^{\circ}>\Delta \mathrm{H}_{1}^{\circ}>\Delta \mathrm{H}_{2}^{\circ}>\Delta \mathrm{H}_{3}^{\circ}\)
  3. \(\Delta \mathrm{H}_{3}^{\circ}>\Delta \mathrm{H}_{2}^{\circ}>\Delta \mathrm{H}_{1}^{\circ}>\Delta \mathrm{H}_{4}^{\circ}\)
  4. \(\Delta \mathrm{H}_{2}^{\circ}>\Delta \mathrm{H}_{1}^{\circ}>\Delta \mathrm{H}_{4}^{\circ}>\Delta \mathrm{H}_{3}^{\circ}\)

Answer

(B) H _ 4 ^ > H _ 1 ^ > H _ 2 ^ > H _ 3 ^

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