Oxidising power of chlorine in aqueous solution can be determined by the parameters…

Oxidising power of chlorine in aqueous solution can be determined by the parameters indicated below: 

\(\frac{1}{2} \mathrm{Cl}_{2}(\mathrm{~g}) \xrightarrow{\frac{1}{2} \mathrm{~A}_{d s s} \mathrm{H}^{\infty}} \mathrm{Cl}(\mathrm{~g}) \xrightarrow{\mathrm{A}_{k A} \mathrm{H}^{\infty}}\)

\(\mathrm{Cl}^{-}(\mathrm{g}) \xrightarrow{\Delta_{\mathrm{hmd}} \mathrm{H}^{\mathrm{a}}} \mathrm{Cl}^{-}(\mathrm{aq})\)

The energy involved in the conversion of \(\frac{1}{2} \mathrm{Cl}_{2}(\mathrm{~g})\) to Cl^- (aq)

Using the data,

\(\Delta_{\mathrm{dims}} \mathrm{H}_{\mathrm{Cl}_{2}}^{\prime \prime}=240 \mathrm{~kJ} \mathrm{~mol}^{-1} .\)

\(\Delta_{\mathrm{EA}} \mathrm{H}_{\mathrm{Cl}}=-349 \mathrm{~kJ} \mathrm{~mol}^{-1} .\)

\(\Delta_{\mathrm{hyd}} \mathrm{H}_{\mathrm{cl}}^{e}=-381 \mathrm{~kJ} \mathrm{~mol}^{-1}\) will be: