Standard electrode potentials of few half-cell reactions are given below: MnO 4 – + 8H +…

Chemistry · Class 12 · CBSE — Electrochemistry

Standard electrode potentials of few half-cell reactions are given below:
MnO4– + 8H+ + 5e– → Mn2+ + 4H2O; E° = 1.51 V
Cr2O72– + 14H+ + 6e– →2Cr3+ + 7H2O; E° = 1.33 V
Fe3+ + e– → Fe2+; E° = 0.77 V
Cl2 + 2e– → 2Cl–; E° = 1.36 V
Based on the above information match the column I with column II and mark the appropriate choice.

Column I Column II

(A)

1 mol of MnO4– to Mn2+

(i)

579000 C

(B)

1 mol of Cr2O72– to 2Cr3+

(ii)

193000 C

(C)

1 mol of Fe3+ to Fe2+

(iii)

482500 C

(D)

1 mol of Cl2 to 2Cl–

(iv)

96500 C
  1. (A) → (i), (B) → (ii), (C) → (iii), (D) → (iv)
  2. (A) → (ii), (B) → (iii), (C) → (i), (D) → (iv)
  3. (A) → (iii), (B) → (i), (C) → (iv), (D) → (ii)
  4. (A) → (iv), (B) → (ii), (C) → (iii), (D) → (i)

Answer

(C) (A) → (iii), (B) → (i), (C) → (iv), (D) → (ii)

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