Consider the cell array c|c|c H _ 2 ( Pt ) & H _ 3 O ^ + ( aq ) 1 ~atm & pH =5.5 array |…

Chemistry · JEE Main · NTA ExamsRedox Reactions and Electrochemistry

Consider the cell \(\begin{array}{c|c|c} \mathrm{H}_{2}(\mathrm{Pt}) & \mathrm{H}_{3} \mathrm{O}^{+}(\mathrm{aq}) \\ 1 \mathrm{~atm} & \mathrm{pH}=5.5 \end{array}\left|\left|\begin{array}{l} \mathrm{Ag}^{+} \\ \mathrm{xM} \end{array}\right|\right.\) Ag. The measured EMF of the cell is 1.023 V. What is the value of x ?
\(\mathrm{E}^{0} \mathrm{Ag}^{+}, \mathrm{Ag}\)= + 0.799 V [T = 25°C]
  1. 2 × 10–2 M
  2. 2 × 10–3 M
  3. 1.5 × 10–3 M
  4. 1.5 × 10–2 M

Answer

(A) 2 × 10 –2 M

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