Among the following options, select the option in which each complex in Set-I shows…

Chemistry · JEE Advanced · NTA ExamsCoordination Compounds

Among the following options, select the option in which each complex in Set-I shows geometrical isomerism and the two complexes in Set-II are ionization isomers of each other.
[en = H2NCH2CH2NH2]
  1. Set-I: [Ni(CO)4] and [PdCl2(PPh3)2]
    Set-II: [Co(NH3)5Cl]SO4 and [Co(NH3)5(SO4)]Cl
  2. Set-I: [Co(en)(NH3)2Cl2] and [PdCl2(PPh3)2]
    Set-II: [Co(NH3)6][Cr(CN)6] and[Cr(NH3)6][Co(CN)6]
  3. Set-I: [Co(NH3)3(NO2)3] and [Co(en)2Cl2]
    Set-II: [Co(NH3)5Cl]SO4 and [Co(NH3)5(SO4)]Cl
  4. Set-I: [Cr(NH3)5Cl]Cl2 and [Co(en)(NH3)2Cl2]
    Set-II: [Cr(H2O)6]Cl3 and [Cr(H2O)5Cl]Cl2∙H2O

Answer

(C) Set-I: [Co(NH 3 ) 3 (NO 2 ) 3 ] and [Co( en ) 2 Cl 2 ] Set-II: [Co(NH 3 ) 5 Cl]SO 4 and [Co(NH 3 ) 5 (SO 4 )]Cl

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