C H _ 3 , ~N H _ 2 , O H , ~F Among these nucleophiles, which of the following orders is…

Chemistry · JEE Main · NTA ExamsOrganic Compounds Containing Halogens

\(\stackrel{\ominus}{\mathrm{C}} \mathrm{H}_{3}, \stackrel{\ominus}{\mathrm{~N}} \mathrm{H}_{2}, \stackrel{\ominus}{\mathrm{O}} \mathrm{H}, \stackrel{\ominus}{\mathrm{~F}}\)
Among these nucleophiles, which of the following orders is correct for their nucleophilicity in acetone ?
  1. \(\stackrel{\ominus}{\mathrm{C}} \mathrm{H}_{3}>\stackrel{\ominus}{\mathrm{N}} \mathrm{H}_{2}>\stackrel{\ominus}{\mathrm{O}} \mathrm{H}>\stackrel{\ominus}{\mathrm{F}}\)
  2. \(\mathrm{F}^{-}>\mathrm{OH}^{-}>\mathrm{NH}_{2}^{-}>\mathrm{CH}_{3}^{-}\)
  3. \(\stackrel{\ominus}{\mathrm{O}} \mathrm{H}>\stackrel{\ominus}{\mathrm{N}} \mathrm{H}_{2}>\stackrel{\ominus}{\mathrm{F}}>\stackrel{\ominus}{\mathrm{C}} \mathrm{H}_{3}\)
  4. none of these

Answer

(A) C H _ 3 > N H _ 2 > O H > F

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