The standard electrode potential E^ and its temperature coefficient ( d E^ e d T ) for a…

Chemistry · NEET · NTA ExamsElectrochemistry

The standard electrode potential \(E^{\theta}\) and its temperature coefficient \(\left(\frac{d E^{\mathrm{e}}}{d T}\right)\) for a cell are 2V and \(-5 \times 10^{-4} \mathrm{VK}^{-1}\) at 300 K respectively. The cell reaction is

\(\mathrm{Zn}(\mathrm{~s})+\mathrm{Cu}^{2+}(\mathrm{aq}) \rightarrow \mathrm{Zn}^{2+}(\mathrm{aq})+\mathrm{Cu}(\mathrm{~s})\)

The standard reaction enthalpy \(\left(\Delta_{r} H^{\ominus}\right)\) at 300 K in kJ mol-1 is:

[Use R = 8 JK-1 mol-1 and F = 96,000 C mol-1]

  1. -412.8
  2. -384.0
  3. 206.4
  4. 192.0

Answer

(A) -412.8

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