Addition of X 2 on alkene is electrophilic addition reaction. Reaction proceed through…

Chemistry · JEE Advanced · NTA ExamsAlkyl and Aryl Halides


Addition of X2 on alkene is electrophilic addition reaction. Reaction proceed through the formation of 3-membered cyclic halonium ion. Nucleophile X attacks from backside of cyclic halonium ion hence total reaction is anti addition reaction. If this reaction proceed in polar solvent then solvent itself acts as nucleophile.
 
Mechanism :
 
 
\(\xrightarrow[\mathrm{CCl}_{4}]{\mathrm{Cl}_{2} \text { (1Mole) }}\)

Answer

(B)

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