Test (Q). A compound X was fused with Na metal and the extract gave a white precipitate…
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Test (Q). A compound X was fused with Na metal and the extract gave a white precipitate with AgNO3. The Lassaigne’s extract gave a red colouration with neutral FeCl3.
Test (R). While compound Y when fused with Na metal and subsequent analysis on its Lassaigne’s extract did not give any characteristic test.
Test (S). While compound Y on fusion with fusion mixture (sodium carbonate + potassium nitrate) or Na2O2, followed by extraction, followed by addition of Conc. HNO3 and ammonium molybdate gave a yellow precipitate.
The chemical reaction taking place in Y, when it is fused with fusion mixture is
- 3Na + P + 4O
Na3PO4 - 3Na2CO3 + 2P + [O]
2Na3PO4 + 3CO2 - 3KNO3 + P + 30
K3PO4 + 3NO2 + O2 - None of these
Answer
(B) 3Na 2 CO 3 + 2P + [O] 2Na 3 PO 4 + 3CO 2
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