500 mL of a 0.05 M Mohr salt solution required the same volume of permanganate solution…

Chemistry · JEE Advanced · NTA ExamsSome Basic Concepts in Chemistry

500 mL of a 0.05 M Mohr salt solution required the same volume of permanganate solution for complete oxidation. Which of the followings is (are) true regarding the above redox reaction?
  1. The molarity of KMnO4 must be 0.01 M if the medium is acidic
  2. The molarity of KMnO4 must be 1 M if the medium is basic.
  3. The medium has no role to play in redox reaction.
  4. In the above reaction Fe(II) is oxidized to Fe(III) irrespective of medium.

Answer

(A) The molarity of KMnO 4 must be 0.01 M if the medium is acidic, (D) In the above reaction Fe(II) is oxidized to Fe(III) irrespective of medium.

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