Often more than one reaction is required to change starting materials into the desired…

Chemistry · JEE Advanced · NTA ExamsSome Basic Concepts in Chemistry


Often more than one reaction is required to change starting materials into the desired product. This is true for many reaction that we carry out in the laboratory and for many industrial process. These are called sequential reactions. The amount of desired product from each reaction is taken as the starting material for the next reaction.
I : 2KClO32KCl + 3O2
II : 4Al + 3O2 2Al2 O3
KClO3 decomposes in step I to give O2, which in turn, is used by Al to form Al2O3 in step II. First we determine O2 formed in step I and then Al used by this O2 in step II. Both reactions can be added to determine amount of KClO3 that can give required amount of O2 needed for Al.
Net : 2KClO3 + 4Al 2KCl + 2Al2O3
Thus, 2KClO3 ≡ 4Al
Or KClO3 ≡ 2Al.
I : CaO + 3C CaC2 + CO
II : CaC2 + 2H2O Ca(OH)2 + C2H2
CaC2 (calcium carbide) is prepared in step I. It is used to prepare acetylene (C2H2) in step II. Suppose we want to determine amount of CaO that can give enough CaC2 to converted required amount of C2H2. Amount of CaO is determined in step I and then amount of C2H2 in step II. We can relate CaO and C2H2 stoichiometrically by writing net reaction which is
CaO + 3C + 2H2 O Ca(OH)2 + C2H2 + CO
Thus, CaO ≡ C2H2
The following process has been used to obtain iodine from oil-field brines in California.
NaI + AgNO3 AgI + NaNO3
AgI + Fe FeI2 + Ag
FeI2 + Cl2 FeCl3 + I2
If 381 kg of iodine is produced per hour then mass of AgNO3 required per hour will be
[atomic mass Ag– 108, I– 127, Fe–56, N–14, Cl–35.5]
  1. 170 kg
  2. 340 kg
  3. 255 kg
  4. 510 kg

Answer

(D) 510 kg

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