E ° Mn 3+ /Mn 2+ is highly positive than that of E ° Cr 3+ /Cr 2+ or E ° Fe 3+ /Fe 2+…

Chemistry · Class 12 · CBSEThe d- and f-Block Elements

E°Mn3+/Mn2+ is highly positive than that of E°Cr3+/Cr2+ or E°Fe3+/Fe2+ because
  1. Mn2+ (d5) can be easily oxidised to Mn3+(d4) due to low ionisation enthalpy
  2. third ionisation enthalpy of Mn is much larger due to stable half filled d5 electronic configuration of Mn2+
  3. Mn3+ is more stable than Mn2+ due to higher oxidation state.
  4. second ionisation enthalpy of Mn is higher than third ionisation enthalpy.

Answer

(B) third ionisation enthalpy of Mn is much larger due to stable half filled d 5 electronic configuration of Mn 2+

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